It cannot be used above 50 degree because the Hg2Cl2 breaks down,yielding an
unstable readings.
Mercurous chloride used in calomel electrode is a toxic substance
It cannot be used above 50 degree because the Hg2Cl2 breaks down,yielding an unstable readings. Mercurous chloride used in calomel electrode is a toxic substance
because calomel act as a reference electrode
246 mV
because that tip of the calomel electrode is made up of porous nature..If we keep it in environment, its get oxidised,,
It consists of tube in the bottom of which is a layer of mercury ,over which is placed a paste of Hg+HgCl2.The remaining portion of cell is filled with a solution of normal or decinormal or saturated solution of KCl. a platinum wire dipping into the mercury layer is used for making electrical contact. the side tube is used for electrode is formulated as;Hg,Hg2Cl2,KCl. the electrode can be coupled with the hydrogen electrode of unknown pH.
For example, the silver/silver chloride electrode (without mercury).
SCE can act as both anode and cathode according to the nature of other electrode.
(UK) ACM, scimed, Sentek
Walter Fieldhouse Clarke has written: 'I. A study of the hydrogen electrode, of the calomel electrode and of contact potential. II. A study of the ethylene electrode. III. Studies in oxidation and reduction ..' -- subject(s): Accessible book, Electrolysis
Standard electrode potential is a redox electrode. This is the forms the basis of the thermodynamic scale.
No, Use a Mercury Oxide electrode in alkalai Media. Strong NaOH will damage glass. Available from Koslow Scientific Co.
They cost extra.