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Make sure it is clean (if your sample will come in contact with it) and functioning properly.

Other than that, it depends very much on what type of equipment you are specifically referring too. Some instruments need to warm up before use, glassware should be cleaned and dried, and you may want to weigh certain flasks and beakers if you will need to later know the mass of what is inside.

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Q: What is the first thing to do before using measuring equipment in chemistry?
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