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I assume you mean 32.0 grams of NaOH and 450 milliliters of NaOH.

Molarity = moles of solute/Liters of solution ( 450 ml = 0.450 liters )

get moles of NaOH

32.0 grams NaOH (1 mole NaOH/39.998 grams)

= 0.800 moles NaOH

Molarity = 0.800 moles NaOH/0.450 liters

= 1.78 Molar NaOH

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