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When addressing a female mayor and multiple council members, it is good form , regardless of gender, to address the mayor first. An example would be: The honorable (insert formal name), Mayor of(name of city) and members of the (name of city) City Council.
Senator Doe,
addressing attorney and wife
vmrs
No honorific is required when addressing the former chairman of a committee.
'Mister Charman,' or 'Madam Chairman' or "Sir' or 'Ma'am.'
The proper salutation for a psychologist is "Dr." if they hold a doctoral degree (PhD or PsyD) or "Mr." or "Ms." if they do not have a doctoral degree. It is always best to refer to them based on their level of education and preference.
Mr for males and Miss, Ms or Mrs for a female.
The proper salutation for a retired General is "General (Retired)" or "General Smith (Retired)" when addressing them formally.
Mister or Madam Chairman, or for a more inclusive term, Sofa-Person.
I believe in a report you should say for an example the president Mr. Barack Obama.
The proper salutation in English for either a medical doctor or the holder of a Ph.D. is the same for either male or female. It is simply "Doctor".