James Madison was the President for whom Monroe served as Secretary of State. (He also served as Madison's Secretary of War for a year or so.)
During President George Washington's terms, he had two secretaries serving him. In 1794 Edmund Randolph served as Secretary of State, and in 1789, Thomas Jefferson served as Secretary of State.
Madeline Albright was Secretary of State during Clinton's second term.
No ex-president has later become a Secretary of State- six have moved up from Secretary of State to president, however.
James Monroe held both of these two positions for a year or so under President James Madison. He served as Secretary of State for all of Madison's administration.
James Monroe served as Secretary of State and as Secretary of War under Madison. For some of the time, he held both positions at once.
John Quincy Adams
James Madison was the President for whom Monroe served as Secretary of State. (He also served as Madison's Secretary of War for a year or so.)
Henry Kissinger served as Secretary of State under both the Nixon and Ford administrations. He is a diplomat and a recipient of the Nobel Peace Prize.
James Madison had 2 secretaries of state during his tenure. Robert Smith served from 1809 - 1811, and James Monroe served from 1811 - 1817.
US President James Madison served as Secretary of State under Thomas Jefferson. There is no records showing him to have served as a Vice President.
James Monroe, the Fifth US President was the Seventh Secretary of State and the Eigth Secretary of War.