Yes. Bolivia won its independence from Spain in 1825.
August 6th 1825
Independence was won in 1825 by Bolivia, which gained its freedom from Spanish colonial rule. The struggle for independence in Bolivia was part of a larger movement across South America during the early 19th century, led by figures such as Simón Bolívar and Antonio José de Sucre. Bolivia officially declared independence on August 6, 1825, marking the culmination of years of conflict and revolutionary efforts.
Simón Bolívar led the fight for independence. In 1819 he defeated the Spainish and won freedom for the present day countries of Venezuela, Colombia, Ecuador, and Bolivia.
He was a Viceroy, appointed by the Spanish Crown. The last viceroy of the New Spain, before it became Mexico, was Juan O'Donoju (1762-1821)
--------Bolivia was named for Simon Bolivar: From Wikipedia: Independence was proclaimed in 1809, but sixteen years of struggle followed before the establishment of the republic, named for Simón Bolívar, on August 6, 1825 (see Bolivian War of Independence). From Infoplease: The country won its independence in 1825 and was named after Simón Bolívar, the famous liberator. From the CIA World Factbook: Bolivia, named after independence fighter Simon BOLIVAR, broke away from Spanish rule in 1825; much of its subsequent history has consisted of a series of nearly 200 coups and countercoups. From the World Atlas: In 1809, the "Liberator," Simon Bolivar (Bolivia's namesake) began the battle for independence, and after the Spanish defeat in 1824, Bolivia finally gained its hard-fough freedom in 1825. From the Encyclopaedia Britannica Online: In recognition of Bolívar's support, congressional leaders named the new republic Bolivia in his honour.
They were ruled by the UK and won their independence from them on July 10, 1973.
Texas won their independence at the Battle of San Jacinto.
Bolivia has never won an Olympic medal.
Bolivia have qualified for a world cup. But they have not yet won it.
The Spanish Empire
So far until the 2008 Olympics Bolivia have not won a gold medal.