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Although nuclear waste in the spent fuel is dangerous to life, it doesn't produce enough thermal output to make this feasible. In an operating reactor a few percent of the reactor thermal output is in fact from the decay of fission products, and when a reactor is shutdown this heat has to be removed, so that emergency heat removal circuits are provided for situations where the main cooling pumps are not available. However the short lived waste soon decays, and the long lived material doesn't produce much power although still dangerous to life. The most it could do would be to heat water for heating of houses, but who would want nuclear waste in their basement? And in any case this would not be allowed under licensing controls, at present in the US nuclear waste is kept on the power station sites, because there is no agreed and licensed way of taking it anywhere else.

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Q: Why can't you use nuclear wastes radiation to generate power?
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