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potassium chloride
When an aqueous solution of sodium hydroxide is electrolyzed, hydrogen is produced at the cathode because hydrogen can be produced at a lower voltage than can sodium, and the supply of hydrogen from the water of the solution is sufficient to consume all the current supplied. When molten sodium chloride is electrolyzed, however, sodium is produced at the cathode.
Hydroxide is not an element. Instead, it is a polyatomic anion that contains the two elements hydrogen and oxygen.
ammonium chloride is moist
Usually hydrogen will evolve from the cathode and oxygen from the anode, but if zinc is the anode, it may dissolve to produce zinc ions in the solution either instead of or along with oxygen evolving.
Sodium metal can be obtained by electrolysis from molten mixture of sodium chloride and calcium chloride in Down's cell. The metal can not be obtained by electrolysis from aqueous solution, because hydrogen will evolve instead.
potassium chloride
No, because sodium chloride isn't alkaline; you could use sodium hydroxide instead of potassium hydroxide (lye) but sodium chloride wouldn't work very well.
Molten salt electrolysis is used to obtain sodium and chlorine. Electrolysis of the water solution is used to obtain sodium hydroxide and hydrogen.
When an aqueous solution of sodium hydroxide is electrolyzed, hydrogen is produced at the cathode because hydrogen can be produced at a lower voltage than can sodium, and the supply of hydrogen from the water of the solution is sufficient to consume all the current supplied. When molten sodium chloride is electrolyzed, however, sodium is produced at the cathode.
If you are asking for the difference between the electrolysis of concentrated NaCl and aqueous NaCl, the water molecules in aqueous NaCl undergoes the Redox reactions rather than the sodium and chloride ions because the electric potential is higher. In concentrated NaCl, the chlorine atoms are oxidised instead.
when an aqueous solution is used, hydrogen gas is evolved at cathode, instead of depositing sodium metal.
Hydroxide is not an element. Instead, it is a polyatomic anion that contains the two elements hydrogen and oxygen.
Sodium Hydroxide is way too basic (very high pH) and would cause internal damage.
aluminum chloride
It would be predicted that it would smell like ammonia, but when performing the actual test myself I found no odor change. I would probably predict a possible pH change. It would be predicted that it would smell like ammonia, but when performing the actual test myself I found no odor change. I would probably predict a possible pH change.
In reference to Electrolysis, the chloride anomaly is the tendency for chloride ions to react with the water molecules in an electrolytic cell which defies the common trend of oxidation and reducing agents to react with the most similar electrode potential. Specific Example: NaCl and Water with graphite electrodes. Predicted Reactions: H2O + e- => 1/2H2 + OH- 1/2O2 + 2H+ + 2e- => H20 Chloride anomaly means this happens instead: H2O + e- => 1/2H2 + OH- Cl- => 1/2 Cl2 + e-