When an aqueous solution of sodium hydroxide is electrolyzed, hydrogen is produced at the cathode because hydrogen can be produced at a lower voltage than can sodium, and the supply of hydrogen from the water of the solution is sufficient to consume all the current supplied. When molten sodium chloride is electrolyzed, however, sodium is produced at the cathode.
NaCl itself will not render any hydrogen, however you can separate hydrogen from the water through the process of electrolysis. During electrolysis of NaCl solution, hydrogen will be evolved at cathode.
lithium
Electrolysis of water gives off Hydrogen at the cathode (-ve chrged terminal).
Usually hydrogen will evolve from the cathode and oxygen from the anode, but if zinc is the anode, it may dissolve to produce zinc ions in the solution either instead of or along with oxygen evolving.
Then use electrolysis to transfer all the copper from the impure anode to the cathode.
NaCl itself will not render any hydrogen, however you can separate hydrogen from the water through the process of electrolysis. During electrolysis of NaCl solution, hydrogen will be evolved at cathode.
lithium
I think the cathode will be coated in silver.
Electrolysis of water gives off Hydrogen at the cathode (-ve chrged terminal).
Sodium metal can be obtained by electrolysis from molten mixture of sodium chloride and calcium chloride in Down's cell. The metal can not be obtained by electrolysis from aqueous solution, because hydrogen will evolve instead.
Electrolysis of water produces hydrogen and oxygen gases at different electrodes. 2H2O(l) --> 2H2(g) + O2(g) Hydrogen is collected at the cathode (-pole). Oxygen is collected at the anode (+pole).
Cathode - Hydrogen Anode - Oxygen
when an aqueous solution is used, hydrogen gas is evolved at cathode, instead of depositing sodium metal.
This depends on what you are electrolyzing. Water, the most common electrolyte, (the material being electrolyzed) separates into Hydrogen molecules on the cathode and Oxygen molecules at the anode. These gasses will bubble up to the top of the electrolysis chamber where they can be collected.
When gaseous hydrogen and gaseous chlorine are mixed each other, they react vigorously to form hydrogen chloride (HCl). The only way to separate elements from the gas HCl is electrolysis where chlorine is discharged at cathode and the other at anode.
Hydrogen gas would evolve from the cathode and oxygen gas would evolve from the anode.
In molten sodium chloride the free moving particles are Na+ and Cl- ions, during electrolysis sodium ion moves towards cathode and chloride ion towards anode.