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When an aqueous solution of sodium hydroxide is electrolyzed, hydrogen is produced at the cathode because hydrogen can be produced at a lower voltage than can sodium, and the supply of hydrogen from the water of the solution is sufficient to consume all the current supplied. When molten sodium chloride is electrolyzed, however, sodium is produced at the cathode.

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Q: Why is hydrogen collected at cathode instead of sodium during the electrolysis of sodium chloride?
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Can you separate hydrogen in the sodium chloride solution?

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