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There is nothing mysterious about this. Dogs and cats do not like having water thrown in their faces for the same reasons that human beings do not like having water thrown in their faces. You, personally, probably do not like having water thrown in your face, unless you are very overheated. And let us remember, a human being with a wet face usually has the opportunity to dry off his or her face with a towel; animals do not have that opportunity.

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Q: Why do cats and dogs react so strongly to water being thrown in their faces?
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