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Because when you eat food you digest it and enegry is released. What bondings are broken determines how much enegry (calories) the food contains.

Fat has ca. 9 cal per gram

protein has ca. 4 cal per gram

carbohydrated ca. 4 cal per gram

alcohol ca. 7 cal per gram

Food that have a lot of water in them have less calories as more of the calories per 100 g are grams of water - i.e no calories. Less water would make a food more "calorie dense" of "caloric".

Worth noting is that your body will require more energy to burn calories from protein than carbs and fat, so if you are dieting eating protein is important to increase metabolism as well as for preservation of muscle mass.

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Q: Why do some foods have so many calories?
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