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Sodium is an element which has one electron in its outer electron shell, and which can obtain a more stable electron configuration by getting rid of that electron. This causes it to undergo chemical reactions with other elements such as oxygen or chlorine, which need to acquire electrons in order to obtain a more stable electron configuration. If sodium reacts with water, it is reacting with the oxygen in the water molecule. In the case of sodium chloride, the sodium has already reacted with chlorine to form that compound, and has given up its outer electron, so it no longer needs to react with oxygen in water.

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Q: Why does metallic sodium react violently with water while sodium chloride does not?
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