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The changes that take place in the red cell as it traverses the body's capillaries (such as exchange of oxygen and carbon dioxide), lead to a slight increase in red cell osmolarity in the venous blood (ie, there are more molecular particles inside the red cell). This causes the movement of extra water into the red cell (via a process called osmosis), causing them to swell slightly (and increasing the red cell's volume). As haematocrit is equal to the red cell volume divided by the entire blood volume, this leads to a slightly higher haematocrit in venous blood as opposed to arterial blood.

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Q: Why haematocrit is more in venous blood?
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pulmonary arterial blood as it has moce CO2 than venous


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