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Pyridine itself (unsubstituted) is basic due to presence of lone pare of electron on nitrogen atom which is not involved in aromatic character , methyl at 4th (Para) position is electron donor due to hyper-conjugation so electrons density at nitrogen becomes increase so 4-methyl pyridine is more basic as compare to unsubstituted pyridine.

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Q: Why is 4 methyl pyridine more basic?
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