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The CH3CH2CH2CH2OH molecules can form strong hydrogen bonds with each other due to the presence of the lone pairs of electrons on O and the H atom which is bonded to the O atom, while CH3CH2CH2CH2SH molecules are unable to due to the absence of H atoms bonded to either F, O or N atoms. As such, more heat energy is required to overcome the stronger hydrogen bonds and thus CH3CH2CH2CH2OH has a higher bioling point.

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Q: Why is the boiling point for ch3ch2ch2ch2oh higher than the boiling point for ch3ch2ch2ch2sh?
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