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With most metals which display more than one oxidation state, the lower oxidation states usually display more ionic behavior than the higher states. This is because more energy is required to lose more electrons. To form Pb+4 would require the loss of 4 electrons, which would require much more energy than to lose two electrons to form Pb+2. Also the highly charged Pb+4 would tend to pull anions close to it favoring covalent bonding. Therefore Pb(IV) compounds may be best described as covalent, while Pb(II) compounds are more ionic. A similar behavior may be seen with manganese oxides. MnO is an ionic, basic oxide similar to MgO. However, Mn2O7 is a covalent, acidic oxide similar to SO3.

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Q: Why lead dichoride is ionic and lead tetrachloride is covalent?
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Molecules can be ionic OR covalent, but not both. PbI2 (lead iodine), however, is ionic.


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Within a single formula unit of lead(IV) perchlorate, you will find both ionic and covalent bonds. The perchlorate polyatomic ion has the formula ClO4(-1) and within that structure, the bonds are covalent because chlorine and oxygen are both non-metals. However, when that unit bonds with lead in a 4:1 ratio, the bond has more ionic character because lead is a metal.


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Ionic or metallic compounds do not contain covalent bonds. Ex. Salt (ionic) or steel/iron/lead (metallic)


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What charge does lead have when it forms a ion?

Lead is a metal with an electronegativity of 2.33. This is very high for a metal. A simple prediction is that reactions with non metals of low electronegativity will form covalent bonds and with non metals of high electronegativity will form bonds which are ionic /covalent borderline. This is essentially what is found, for example, PbO is more ionic than PbS. PbS is essentially ionic but is also a semiconductor- so there is a covalent component to the bonding. Lead has two oxidation states, lead(II) and lead(IV). the more stable state is lead(II). The first two ionization energies are similar to magnesium. Lead forms Pb2+ salts such as Pb(NO3)2 unlike most lead(II) salts this is soluble in water, and PbSO4 (found in car batteries), which is insoluble, and PbCO3 another insoluble salt called white lead when it was used in paints. Lead(IV) compounds are not generally ionic - the ion Pb4+ would be highly polarising and would lead to covalent bonding, PbF4 is the most ionic - it is a high melting solid with a structure like SnF4. It is thermally unstable decomposing to produce fluorine.


Why Pbcl2 is ionic and Pbcl4 is covalent?

apply fazan's rule, greater the charge on cation more is the polarising power and hence more covalent character polarising power of pb4+>pb2+ thus pbcl4 is more covalent than pbcl2 conversely pbcl2 more ionic than pbcl4


What is the dissolution equation of PbCl2?

PbCl4 is it's formula. The name of the chemical is Lead tetrachloride.