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I do believe that since methanol (CH3OH) is a smaller molecule than ethanol (C2H5OH), and alcohol loses its polarity (and its ability to dissolve polar molecules as well as its own miscibility in water, also a polar molecule) at around 5 carbons or so, then it would follow that perhaps methanol is better at grabbing onto those polar compounds you'd like to extract. Ethanol usually works just fine for long term extraction, and provides a product we can consume.

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Q: Why methanol gives better yield than ethanol?
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