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In pyridine molecule the Nitrogen atom is involved in Aromatic character of ring if lone pair of nitrogen forms a sigma bond with hydrogen the Aromatic ring (Aromaticity) becomes lass stable so pyridine do not accept the proton easily while Aromaticity is not involved in pi-pyridine so its nitrogen atom easily donates the electron pair to a proton .

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10y ago
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1w ago

Pyridine is less basic than piperidine because the nitrogen in pyridine is part of an aromatic ring, which delocalizes the lone pair of electrons on the nitrogen atom and makes it less available for proton donation. In contrast, piperidine has a more localized lone pair on the nitrogen atom, making it more readily available for proton donation, thus making piperidine a stronger base than pyridine.

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14y ago

Pyridine N is sp2 hydridized, it's lone pair is less available than Piperdine N which is sp3 hydridized

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Q: Why pyridine is less basic than piperidine?
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Why pyrrole is less basic than pyridine?

Pyrrole is less basic than pyridine because the lone pair of electrons on the nitrogen in pyrrole is part of the aromatic system and less available for donation compared to the lone pair on the nitrogen in pyridine. This makes pyridine more basic than pyrrole.


Why pyrrole is more acidic and less basic than pyrrolidine?

Pyrrole is more acidic than pyrrolidine because the nitrogen lone pair in pyrrole is part of the aromatic ring, making it less available for protonation. Pyrrolidine is less acidic and more basic than pyrrole because the nitrogen lone pair is not part of an aromatic system, allowing it to readily accept a proton.


Which is more basic pyridine or quinoline?

Pyridine is more basic than quinoline. This is because the nitrogen atom in pyridine is more readily available to accept a proton compared to the nitrogen in quinoline due to the presence of an additional ring in quinoline which delocalizes the lone pair of electrons on the nitrogen atom, making it less basic.


Which is more basic pyridine or pyrrolidine?

Pyridine is more basic than pyrrolidine. This is because pyridine has a lone pair of electrons on the nitrogen atom in the aromatic ring, which is more available for donation to accept a proton and act as a base compared to pyrrolidine, which has one of its nitrogen lone pairs delocalized in the aromatic ring.


Pyrrole is weaker base than pyridine?

This is because pyrrole is a more acidic compound due to the presence of an acidic hydrogen on the nitrogen atom in the aromatic ring, making it less likely to act as a base compared to pyridine which does not have an acidic hydrogen. In pyridine, the lone pair of electrons on the nitrogen atom is more available for donation, making it a stronger base.

Related questions

Why pyrrole is more acidic and less basic than pyrrolidine?

Pyrrole is more acidic than pyrrolidine because the nitrogen lone pair in pyrrole is part of the aromatic ring, making it less available for protonation. Pyrrolidine is less acidic and more basic than pyrrole because the nitrogen lone pair is not part of an aromatic system, allowing it to readily accept a proton.


Can you get less than Basic Cable with comcast?

Limited basic.


Why do 5-membered ring aromatic heterocycles pyrrole and furan undergo electrophilic substitution more rapidly than benzene while 6-membered ring heterocycles like pyridine are less reactive than Benz?

5-membered ring heterocycles like pyrrole and furan have greater reactivity due to their higher electron density compared to benzene, making them more susceptible to attack by electrophiles. In contrast, the nitrogen atom in pyridine stabilizes the ring by delocalizing the lone pair of electrons, reducing its reactivity towards electrophilic substitution reactions.


Is a pH of 8 more basic or less than a pH of 6?

The higher the pH, the more basic, so a pH of 8 is more basic than a pH of 6.


Synthesis of propylpyrdine?

The synthesis of the propyl pyridine is done using 2-propanol other than the zeolites.


A solution whose pH is 9.0?

This would represent a mild base (or basic) solution. Greater than 7.0 = basic. Less than 7.0 = acidic.


What is more than 2 and less than 3?

In a basic sense, anywhere between 2.01 and 2.99.


Pyrrole is weaker base than pyridine?

This is because pyrrole is a more acidic compound due to the presence of an acidic hydrogen on the nitrogen atom in the aromatic ring, making it less likely to act as a base compared to pyridine which does not have an acidic hydrogen. In pyridine, the lone pair of electrons on the nitrogen atom is more available for donation, making it a stronger base.


The pH of acids and bases?

7.0 is neutral. Less than 7.0 is acidic. More than 7.0 is basic/alkaline.


Is physiological pH about 7.4?

Yes, physiological pH for arterial blood is around 7.4, which is slightly alkaline. This pH range is crucial for the proper functioning of enzymes and other biochemical processes in the body. Any significant deviation from this range can lead to health issues.


How do you determine if an compound is acidic or basic?

The acidity or basicity of a compound is determined by its ability to donate or accept protons (H+ ions). Compounds that release protons in solution are considered acidic, while those that accept protons are considered basic. The pH scale can be used to quantitatively measure the acidity or basicity of a compound, with values below 7 indicating acidity and values above 7 indicating basicity.


Where would Ajax be on the pH scale?

Ajax is a cleaning product with a pH of around 10-12, making it alkaline. On the pH scale, a pH of 7 is neutral, so Ajax would be considered basic or alkaline.