because the pH change involved is very small and it is generally difficult to find the end point
If you are titrating a base, using a weak acid as titrant would lead to the formation of a buffer as you added the weak acid. The weak acid would react with the base to form the salt of the weak acid + water, and this would buffer any changes in pH, thus making the titration meaningless.
The formic acid is a weak acid.
In order to have an effective buffer, one needs to have a weak acid or a weak base, and the salt (conjugate) of that weak acid or weak base. Examples would be :weak acid/conjugate base: acetic acid/sodium acetateweak base/conjugate acid: ammonia/ammonium chloride
You need to know the volume of the weak acid being titrated so you can find how many moles of base are needed to match that of the acid.
Use a method called titration, where a known concentration of either a strong acid (to measure a weak base) or a strong base (to measure a weak acid) is slowly added to a solution of the unknown compound. By measuring the pH of the solution as you do the titration, and by measuring the volume of the known solution that you added to the unknown, you can determine the pKa of the unknown compound.For complete instructions on how a titration is performed, see the Web Links to the left of this answer.how can i determine pka value if pH is given?
the factors are - 1. the kind of titration ie strong acid -strong base,strong acid -weak base,weak acid-strong base,weakacid -weak base. 2.the endpoint 3. the rate of rxn
There is no 'sharp' end of this reaction (= all parts have unambigiously reacted with a well determined conterpart)
a strong acid and a weak base.
Titration is the controlled neutralisation of an acid and a base. If the titration is done using a weak acid and a strong base, it can be analysed in detail and all concentrations of the aqueous species at any volume addition of the titrant can be determined.
It is difficult to determine the end point of such a titration, because the titration produces a buffer solution that changes its pH very slowly at the end point, in contrast to reaction between a strong acid and strong base.
alkaline obviously! strong acid + strong base= neutral strong acid + weak base= acidic weak acid + strong base= alkaline
For strong acid/strong base reactions: pH 7 is the equivalence point For titration of a weak base with strong acid : pH 6-3 is the equivalence point For titration of a weak acid with strong base : pH 8-11 is the equivalence point For weak acid/weak base reactions it is also around pH 7, but it happens so NON-sharply, vague, that titrations can't be used for these.
Phenopthalene is used commonly
Phenolphtalein is an indicator used to find the endpoint of a reaction (specifically an acid-base reaction). It has a pH range of 8.3 to 10.0 which means it can be used for a strong acid to strong base titration or a weak base to strong acid titration. Phenolphthalein is clear when it is in the presence of acid and pink when it is in the presence of a base.
It is the nearly horizontal region before the equivalence point.
It is difficult to determine the end point of such a titration, because the titration produces a buffer solution that changes its pH very slowly at the end point, in contrast to reaction between a strong acid and strong base.
It depends on the acid or base used. For strong acid vs. strong base, phenolphthalein can be used as indicator. For strong acid vs. weak base, methyl orange can be used as indicator. For weak acid vs. strong base, phenolphthalein can be used as indicator.