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That sounds like a really risky thing to do I would personally not try it because white spirits are a petroleum product and this clashes with acrylics. If you feel that the surface needs cleaning prior to painting it I would be more inclined to use some sort of alcohol based thinners that agrees with acrylics..

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Q: Will cleaning down a pool with white spirit prior to painting it with acrylic water based pool paint cause it to peal if allowed to completely dry before painting?
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