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The glass of a windshield cools down overnight much faster than other objects. Being morehorizontalthan the side windows on a car allows cooler, denser air to settle and condense against it more so than vertical surfaces. Frost forms when this condensation happens from water vapor in the air directly to the frozen, solid state. Frost rarely forms if dew has formed, or if there is much of a breeze.

Measuring the temperature at a frosted windshield will show that it did get to (or just under) the freezing point, even though the heat radiating up from the ground has kept the ambient air's temperature above freezing. Radiant heat from the ground and surrounding objects also plays a part in the side windows staying a bit warmer than the windshield who's surface is facing the sky (and falling cold air).

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