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This question is tricky because distance and location are not well defined within the electron cloud. So for the sake of explanation, let us assume that the question is "Which has a region maximum probability closest to the nucleus?"

I could not find an answer in print for the 4f vs 6s. However, I did find an answer comparing the 3d and 4s. I believe that an understanding of a comparison between the 3d and 4s can be extended to a comparison between the 4f and 6s.

The most probable distance of the 3d is less than the 4s. Therefore, we could extend this and say that most likely the 4f sublevel would have a distance of maximum probability closer than the 6s.

You did not ask why so I will not go into an explanation.

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Q: Would the 4f orbital or 6s orbital be closer to the nucleus?
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Which orbital electron has the highest energy?

I would think the s orbital, because it is closer to the nucleus, and because the outer energy level holds more energy than the inner ones.


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