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This is because of the polarity of the solvents. Aqueous solution (H2O) is very polar and will produce H+ ions when HCL is added, thus resulting in a acidic solution. On the other hand, benzene, a nonpolar solvent will not produce H+ ions and no acidic properties.

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Q: Aqueous solution of gaseous HCl is acidic but solution of HCl gas in benzene has no acidic property?
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