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First balance Carbon (add 4 at right side, 4=4)

C4H10 --> 4 CO2 + H2O

Then balance Hydrogen (add 5 at right side, 10=5*2 )

C4H10 --> 4 CO2 + 5 H2O

Then balance Oxygen (add 6.5 O2 at left side, (4*2 + 5)right = 13 = (6.5*2)left

C4H10 + 6.5 O2 --> 4 CO2 + 5 H2O

Multply both siide by 2 to prevent halved quantities

2 C4H10 + 13 O2 --> 8 CO2 + 10 H2O

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