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Assuming that you are talking about Chloral Hydrate as in (C2H3Cl3O2) this shouldn't be too hard to answer.

We are give 5.0g of C2H3Cl3O2 so we need to convert that into atoms, then moles.

First set up the equation 5.0g*1mole/165.40g [<-molar mass] *6.02x10^23 molecules / 1 mole*3atoms Cl/1molecule. [You should get 5.46x10^22]

If you solve that, you will come up with the total number of Cl atoms in C2H3Cl3O2 so from there just convert that into moles using avagadro's number

5.46x10^22atoms Cl/1*1mole/6.02x10^23atoms

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