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Copied from dictionary.com (accessed March 1, 2012): vitamin: any of a group of organic substances essential in small quantities to normal metabolism, found in minute amounts in natural foodstuffs or sometimes produced synthetically: deficiencies of vitamins produce specific disorders.

Fluoride - refers to the F- anion. Sodium fluoride (for example, in a varnish) is an inorganic compound. The fluoride ion is not essential to any known normal metabolic process. A deficiency of fluoride has never been shown to produce any specific disorders.

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