Benzoate indicates a COO- group attached to the benzene ring. This is a deactivating group and deactivates the benzene ring as well as is a meta directing group.
Hence, two products could form.
1. Monosubstitution - results in 3-nitromethylbenzoate
2. Disubstitution - results in 3,5-dinitromethylbenzoate
Concentrated sulfuric acid serves as a catalyst in the nitration of methyl benzoate. It helps in protonating the nitric acid to form a stronger electrophile, the nitronium ion, which then attacks the aromatic ring of methyl benzoate to facilitate the nitration reaction. Additionally, it helps in removing water produced during the reaction to drive the equilibrium towards the product formation.
181gMethyl Benzoate is 136gMethyl benzoate is when you replace one of the hydrogens with a group of NO2NO2 has a mass of= 46gadd this to the mass of the methyl benzoate then take away 1 which is mass of the hydrogen that was replaced
The reaction of methyl benzoate with dilute sulfuric acid generates benzoic acid and methanol as the main products.
The best solvent for methyl benzoate is typically a non-polar solvent such as diethyl ether or dichloromethane. These solvents are effective in dissolving methyl benzoate due to its non-polar nature and facilitate its extraction and purification processes.
Check the book Macroscale and Microscale by Williamson and Masters. Go to the chapter entitled Nitration of Methyl Benzoate. The synthesis of 3-nitrobenzaldehyde/3-nitrobenzoic acid has the same procedure.
Concentrated sulfuric acid serves as a catalyst in the nitration of methyl benzoate. It helps in protonating the nitric acid to form a stronger electrophile, the nitronium ion, which then attacks the aromatic ring of methyl benzoate to facilitate the nitration reaction. Additionally, it helps in removing water produced during the reaction to drive the equilibrium towards the product formation.
181gMethyl Benzoate is 136gMethyl benzoate is when you replace one of the hydrogens with a group of NO2NO2 has a mass of= 46gadd this to the mass of the methyl benzoate then take away 1 which is mass of the hydrogen that was replaced
The reaction of methyl benzoate with dilute sulfuric acid generates benzoic acid and methanol as the main products.
Methyl benzoate, an organic compound, is an ester. It is a colorless liquid that is not soluble in water and has a fruity smells. Some uses for methyl benzoate are as a solvent and a pesticide.
The initial products of saponification of methyl benzoate are the sodium salt of benzoic acid and methanol. The sodium salt of benzoic acid is soluble in water because it forms ionic bonds with water molecules. Methanol is also soluble in water due to its polar nature, allowing it to hydrogen bond with water molecules.
The methyl group on the para position of m-nitrobenzoate is electron-donating, which increases electron density on the benzene ring. This makes the ring less susceptible to further nitration and reduces the likelihood of forming dinitro products.
The best solvent for methyl benzoate is typically a non-polar solvent such as diethyl ether or dichloromethane. These solvents are effective in dissolving methyl benzoate due to its non-polar nature and facilitate its extraction and purification processes.
The ester formed from octyl benzoate is called octyl benzoate. It is formed when octanol reacts with benzoic acid in the presence of a catalyst. This ester is commonly used in cosmetics and personal care products as a fragrance ingredient or UV filter.
Check the book Macroscale and Microscale by Williamson and Masters. Go to the chapter entitled Nitration of Methyl Benzoate. The synthesis of 3-nitrobenzaldehyde/3-nitrobenzoic acid has the same procedure.
To prevent di-nitration of the methy benzoate because COOMe group attached to the aromatic ring is deacitvating, hence, plus the deactivating NO2 group, a higher temperature and more acidic condition would be required to add another NO2 to the 5th carbon of the aromatic ring of the methyl 3-nitrobenzoate
4 methyl (3, 5 dinitro) phenylol
methyl parabenpropyl parabensodium benzoate