Lone pairs will repel slightly more than bond pairs of electrons. Each lone pair will reduce the bond angle expected by around 2.5 degrees, as a general guide. For example, water has four sets of electrons, so if it had those arranged as in methane, which has four bond pairs, we'd expect the bond angle to be 109.5 degrees. However, the lone pairs repel more, decreasing the bond angle down to 104.5 degrees. The theory is called VSEPR theory and is well explained in the excellent website Chemguide.
The molecule NBr3 has a trigonal pyramidal shape. It consists of a central nitrogen atom bonded to three bromine atoms, with one lone pair of electrons on the nitrogen atom. The lone pair causes the shape to be pyramidal rather than planar.
its polar there are two unbonded electrons on the central atom, As (Arsenic) The molecule has eight valence electrons in total from the Hydrogen and Arsenic. Six of these are used for the three bonds, but there are two extra attached to the As. The unbonded electrons have a greater effect on the shape of the molecule, and will skew it so that it is bent. The bonds between the As and H will then combine to form a force that does not balance out. There is a dipole moment, and it is therefore a polar molecule.
Yes, they generally are. In the case of ammonia, NH3, nitrogen has an electron pair and three unpaired electrons (as per Hund's rule.) The pair remains unbonded, but each single electron bonds single-covalently to a hydrogen. The unbonded pair "pushes" the 3 bonded hydrogens downward into a "tripod" shape, making the molecule pyramidal. The molecule is polar because the unbonded pair constitutes a negative partial charge.
Yes it can, if there are no lone, unbonded pairs of electrons around the central atom. Water has 3 atoms, but also has 2 unbonded pairs. It is therefore a bent shape. Carbon dioxide, however, has no unbonded pairs, and is linear with 3 atoms.
An ammonia molecule has a trigonal pyramidal shape, with the nitrogen atom at the center and three hydrogen atoms bonded to it. The lone pair of electrons on the nitrogen atom causes the molecule to be slightly asymmetrical.
The molecule NBr3 has a trigonal pyramidal shape. It consists of a central nitrogen atom bonded to three bromine atoms, with one lone pair of electrons on the nitrogen atom. The lone pair causes the shape to be pyramidal rather than planar.
its polar there are two unbonded electrons on the central atom, As (Arsenic) The molecule has eight valence electrons in total from the Hydrogen and Arsenic. Six of these are used for the three bonds, but there are two extra attached to the As. The unbonded electrons have a greater effect on the shape of the molecule, and will skew it so that it is bent. The bonds between the As and H will then combine to form a force that does not balance out. There is a dipole moment, and it is therefore a polar molecule.
Yes, they generally are. In the case of ammonia, NH3, nitrogen has an electron pair and three unpaired electrons (as per Hund's rule.) The pair remains unbonded, but each single electron bonds single-covalently to a hydrogen. The unbonded pair "pushes" the 3 bonded hydrogens downward into a "tripod" shape, making the molecule pyramidal. The molecule is polar because the unbonded pair constitutes a negative partial charge.
Yes it can, if there are no lone, unbonded pairs of electrons around the central atom. Water has 3 atoms, but also has 2 unbonded pairs. It is therefore a bent shape. Carbon dioxide, however, has no unbonded pairs, and is linear with 3 atoms.
Temperature
Electrons influence the shape of a molecule through their distribution around the nucleus, which affects the bonding between atoms. The sharing or transfer of electrons between atoms makes chemical bonds that determine the geometry of the molecule. The arrangement of electron pairs (bonding and non-bonding) around the central atom determines the molecule's shape according to VSEPR theory.
The shape of this molecule is Trigonal Planar. this is because it has no lone pairs of electrons so it maintains a 2D shape.
Electronegativity influences molecular structure by determining the distribution of electrons within a molecule. Atoms with higher electronegativity tend to attract electrons more strongly, leading to polar covalent bonds and the formation of polar molecules. This can affect the overall shape and properties of the molecule.
A molecule of water has the molecular geometry bent, which results from having 2 bonded pairs of electrons and two unbonded pairs of electrons. As to the polarity, a molecule is either polar or non-polar, based on the difference in the electronegativity values of the atoms present and the overall geometry of the molecule. There is a suficietly large electronegativity difference between the hydrogen atoms and the oxygen atom to create a polar molecule, and a bent geometry will not cancel out this polarity. Thus, water is polar.
An ammonia molecule has a trigonal pyramidal shape, with the nitrogen atom at the center and three hydrogen atoms bonded to it. The lone pair of electrons on the nitrogen atom causes the molecule to be slightly asymmetrical.
The shape of a water molecule (H2O) is bent or angular, resembling a letter "V". This occurs due to the two lone pairs of electrons on the oxygen atom, causing the molecule to have a bent molecular geometry.
A molecule of hydrogen sulfide (H2S) would have a bent shape due to its molecular geometry. It consists of two hydrogen atoms bonded to a sulfur atom with lone pairs of electrons around the sulfur, causing the molecule to bend.