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As particles are heated they will start to vibrate. The vibrations will increase as temperature increases.

As the water temperature increases the particles continue to gain vibrational energy until eventually they all have enough energy to leave the water phase and vaporize. Then the temperature change halts as all the particles have the energy to break apart the inter-molecular forces holding the water molecules together (Hydrogen bonding). Even though there is a heat source, the temperature of the water stays the same as the heat, latent heat of vaporization, is used to break the molecules away from each other to form a gas.

The gas can be heated into super heated steam but the liquid phase will stay at 100oC, or there abouts depending on the atmospheric pressure, until all of the liquid is vaporized.

The same phase change occurs when ice warms. There is a halt in temperature change due to the latent heat of fusion as some of the inter-molecular bonds forming the solid are broken and the liquid is formed.

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