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What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?
-H, +S
What else can I help you with?
Which statement describes a reaction at 298 K if H 31 kJ mol S 0.093 kJ molK?
It is not spontaneous.
What kind of enthalpy change favors a spontaneous reaction?
For a spontaneous reaction, the overall change in enthalpy should be negative (exothermic). This means that the products have a lower enthalpy than the reactants, releasing energy in the form of heat.
How does the Gibbs free energy predict spontaneity?
It tells if the reaction will process spontaneously or not
What can be said about the reaction at 500K?
At 500K, the reaction rate will increase as temperature rises, following the Arrhenius equation. This increase in temperature will also influence the equilibrium position of the reaction if it is a reversible reaction. Higher temperatures can sometimes shift the equilibrium towards the products or reactants, depending on the enthalpy change.
A chemical reaction has a positive ΔH value and a positive ΔS value Under what conditions is the reaction spontaneous?
The reaction will be spontaneous at high temperatures (T) where TΔS > ΔH, according to Gibbs free energy equation, ΔG = ΔH - TΔS. At high enough temperatures, the TΔS term can outweigh the positive ΔH term, leading to a negative ΔG value and a spontaneous reaction.
Which statement describes a reaction at 298 K if H 31 kJ mol S 0.093 kJ molK?
It is not spontaneous.
A chemical reaction has a positive H value and a positive S value Under what conditions is the reaction spontaneous?
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΔG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΔS term outweighs the positive ΔH term, resulting in a negative ΔG. This means the reaction will be spontaneous at elevated temperatures.
What kind of enthalpy change favors a spontaneous reaction?
For a spontaneous reaction, the overall change in enthalpy should be negative (exothermic). This means that the products have a lower enthalpy than the reactants, releasing energy in the form of heat.
What kind of reaction occurs when the entropy change of an endothermic reaction is negative?
The reaction is exothermic
How does the Gibbs free energy predict spontaneity?
It tells if the reaction will process spontaneously or not
What conditions will a low temperature male a reaction spontaneous?
A reaction will be spontaneous at low temperatures if the decrease in enthalpy (change in heat content) of the reaction is greater than the decrease in entropy (measure of disorder) multiplied by the temperature. This can be represented by the equation ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
A chemical reaction has a positive ΔH value and a positive ΔS value Under what conditions is the reaction spontaneous?
The reaction will be spontaneous at high temperatures (T) where TΔS > ΔH, according to Gibbs free energy equation, ΔG = ΔH - TΔS. At high enough temperatures, the TΔS term can outweigh the positive ΔH term, leading to a negative ΔG value and a spontaneous reaction.
What can be said about the reaction at 500K?
At 500K, the reaction rate will increase as temperature rises, following the Arrhenius equation. This increase in temperature will also influence the equilibrium position of the reaction if it is a reversible reaction. Higher temperatures can sometimes shift the equilibrium towards the products or reactants, depending on the enthalpy change.
What is the relationship between enthalpy, entropy, and free energy in a chemical reaction?
In a chemical reaction, enthalpy, entropy, and free energy are related. Enthalpy is the heat energy exchanged during a reaction, entropy is the measure of disorder or randomness, and free energy is the energy available to do work. The relationship between these three factors is described by the Gibbs free energy equation: G H - TS, where G is the change in free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature in Kelvin. This equation shows that for a reaction to be spontaneous, the change in free energy must be negative, meaning that the enthalpy change and entropy change must work together in the right direction.
On what conditions does a spontaneous reaction become spontaneous?
For some non-spontaneous reactions, you can change the temperature. For other non-spontaneous reactions, there is nothing you can do to make it spontaneous. Nature favors reactions that increase a system's entropy (disorder) and nature favors reactions that are exothermic (they release enthalpy). Any reaction that does both of these things is spontaneous at all temperatures. Any reaction that does neither of these things is never spontaneous. As far as this question is concerned, the interesting reactions are endothermic reactions that increase entropy and exothermic reactions that decrease entropy. Whether these reactions are spontaneous depends on the temperature. The first variety (endothermic, increase entropy) will be spontaneous at high temperatures; the second (exothermic, decrease entropy) will be spontaneous at low temperatures. To find the temperature at which a reaction becomes spontaneous, one may apply the Gibbs equation: DG = DH - TDS where capital Ds stand for the Greek capital delta.
What is the relationship between the standard enthalpy of formation and the standard enthalpy of reaction in chemical reactions?
The standard enthalpy of formation is the energy change when one mole of a compound is formed from its elements in their standard states. The standard enthalpy of reaction is the energy change for a reaction under standard conditions. The relationship between the two is that the standard enthalpy of reaction is the sum of the standard enthalpies of formation of the products minus the sum of the standard enthalpies of formation of the reactants.
What value should the heat of the reaction have in a spontaneous reaction?
It can be + or - depending on the value of the entropy (∆S). Recall, that ∆G = ∆H - T∆S and for a spontaneous reaction, ∆G must be negative, so you can see how this will depend on the values and signs of both enthalpy and entropy.
