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sp carbons are more electronegative.

The larger the 's' character of the atom, the closer the electrons are held to the nucleus. sp3 carbons are the least electronegative as the 'p' character forces the electrons to exist further from the nucleus, decreasing electronegativity.

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Q: Which carbon is more electronegative sp3 sp2 sp?
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Why Sp2 carbon is more electronegative than Sp3 carbon?

We should know that S orbitals hold electrons more tightly to nucleus than P orbitals . This implies that S orbitals are effectively more electronegative . Now, in sp2 carbon the character of each orbital has 1/3 or 33% of s orbital characteristics whereas in each sp3 orbital s character is 1/4 or 25% . So sp2 has more s character and therfore more electronegativity. H.Sehgal


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