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In sodium and copper it is the s electrons delocalised accross the lattice that contribute to the electrical conductivity. The extra bonding due to d orbitals in copper, a transition metal, contributes to its hardness and higher melting point .

Both sodium and copper have metallic bonds. Sodium is an alkali metal and there are no d electrons, wheres copper is a transition metal. In the alkali metals the only force of attraction between the metal atoms is due to the delocalisation of the s electrons. In transition metals there is an extra attraction due to the d electrons. Copper has one of the lowest heats of formation of the transition metals the d electrons contribute less than in the lighter members.

Hardness is a poor measure IMHO of metallic bond strength, as hardness can be related to the density of lattice dislocations.

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