More van der Waals' forces to break hence a higher temperature required to break them all
C20h42
This is true as far as we are talking about alkanes. As the size of an alkane chain increases the boiling point increases because the relatively low van der Waals forces increase with mass. The higher the vdw forces the more energy required to break apart two molecules and thus higher boiling points.
smaller and less massive hydrocarbons :)
As the base number of carbon atoms in a simple hydrocarbon increases, the higher the potential energy contained in the compound. More complex hydrocarbons can also have shifting melting and boiling ranges.
The more is the number of carbons in the alkane, the more is its boiling point.REASON:- As the number of carbon increases, the becomes the molecular mass. And the more is the molecular mass, the greater becomes the surface area which increases the van der Waal force of intermolecular attraction thereby increasing the boiling point of the alkane.NOTE:- Among isomers (of the same alkane), the structure which have more # of side chain has less BP because more the # of side chains are present, more will the structure will be closer to the shape of a sphere, therefore will have smaller surface area.-by spd831
C20h42
This is true as far as we are talking about alkanes. As the size of an alkane chain increases the boiling point increases because the relatively low van der Waals forces increase with mass. The higher the vdw forces the more energy required to break apart two molecules and thus higher boiling points.
Yes Since they have a lower boiling point, they have a higher vapor pressure - or to be more exact, a higher fugacity, than the higher boiling point components at the same temperature.
Increasing the number of carbons in a molecule increase the boiling point in the wast majority of cases.
First of all the basic different hydrocarbons are Alkanes, Alkenes , & Alkynes. Their names end in '-ane', '-ene' and 'yne', respectively. There are more complex hydrocarbons, such as Benzene(Phenyl) & 'Cyclo-', but for the moment I'll omit these. Next the number of carbons in the chain gives the basic name. Meth = 1 carbon Eth = 2 carbons Prop = 3 carbons Buta = 4 carbons Penta = 5 carbons Hexa = 6 carbons Hepta = 7 carbons Octa = 8 carbons Nons = 9 carbons Deca = 10 carbons So a hydrocarbon , with single bonds, and with two carbons is Ethane A hydrocarbons, with one double bond and three carbons is Propene A hydrocarbon, with one triple bond and four carbons is either But-1-yne or But-2-yne , depending on which carbon in the chain the the double/triple bond starts at. Petroleum/Gassoline is Octane. Benzene is a 6 carbon cyclic ring, with ,???three double bonds,. This a unique arrangement. Other cyclic hydrocarbons are ;- Cyclohexane , Cyclohexene. and Cyclohex-1,3-diene. There are many more. Hopefully that gives a little insight in to the nomenclature (naming system) of hydrocarbons; The IUPAC authority have designed the nomenclature so that the name gives all the elements, structure and position of the atoms in organic compounds.
smaller and less massive hydrocarbons :)
As the base number of carbon atoms in a simple hydrocarbon increases, the higher the potential energy contained in the compound. More complex hydrocarbons can also have shifting melting and boiling ranges.
The normal boiling point is the boiling point at sea level, or more precisely, at 1 atmosphere pressure. At higher elevations, or at lower atmospheric pressures, the boiling point is lower. At higher atmospheric pressures, the boiling point is higher.
The more is the number of carbons in the alkane, the more is its boiling point.REASON:- As the number of carbon increases, the becomes the molecular mass. And the more is the molecular mass, the greater becomes the surface area which increases the van der Waal force of intermolecular attraction thereby increasing the boiling point of the alkane.NOTE:- Among isomers (of the same alkane), the structure which have more # of side chain has less BP because more the # of side chains are present, more will the structure will be closer to the shape of a sphere, therefore will have smaller surface area.-by spd831
short chain hydrocarbons have a low boiling and melting point whereas high chain hydrocarbons have a higher boiling and melting point. Also, short chain hydrocarbons have a low density and higher ones have a higher density. :)
NormallyGenerally a molecule with with a longer carbon chain has higher boiling compared to that of a shorter carbon-hydrogen chain. This is due to greater intermolecular forces exhibited by the longer chain. This is the reason why a carbon chain which consists of 4 or less carbons are gas at room temperatures; while carbon chains with more than 4 carbons are liquids at room temperatures. Branching however can reduce some of these intermolecular forces as the chains are hindered from approaching in close approximately and packing near each other. The packing is caused by the intermolecular attractions between the alkanes.More »
Straight chain isomers have higher boiling points, so the more branched the isomer the lower the boiling point.