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Ethoxyethane is heavier than propanone and that will surely make a difference. The carbon-oxygen bond in ethers is less polarized than that in aldehydes and ketones. This is because the oxygen in ethers is attached to two electron pushing alkyl groups which account for the oxygen atom's electronegativity. Thus, dipole-dipole interactions are weaker in ethers giving them a lower boiling point than the corresponding aldehyde or ketone.

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8y ago
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12y ago

Because propanoic acid has hydrogen bonding while propanone does not. London Dispersion Force is the weakest intermolecular force then its Dipole-dipole bonding

then Hydrogen Bonding. Since propanone is polar, it has london dispersion force and dipole-dipole and propanoic acid has london dispersion, dipole-dipole and hydrogen bonding so propanoic acid has a stronger intermolecular force therefore it takes more energy to break the bonds apart which means more heat is needed to break the bonds of propanoic acid than propanone.

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11y ago

Iso-propanol has intermolecular hydrogen bonding. So they have higher boiling point than acetone.

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Q: Why does propanone has a higher boiling point than ethoxyethane?
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