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Acidifying iron with H2SO4 during redox titration helps in preventing the hydrolysis of iron(III) ions, which can form insoluble hydroxides and interfere with the titration results. The acid medium also helps to ensure that the redox reaction between the iron and the titrant is carried out effectively and selectively.
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Why do you add H2SO4 instead of HCL in redox titration?
H2SO4 is preferred over HCl in redox titrations because HCl can release Cl2 gas during the reaction, which can interfere with the titration results. H2SO4 provides the necessary acidic conditions for the redox reaction without introducing additional complications.
Why HCL is not use to acidify KMnO4 soln in permanganometric titration?
HCl cannot be used to acidify KMnO4 solution in permanganometric titration because it will react with KMnO4 reducing it to MnO2, which interferes with the titration process and affects the accuracy of the results. Instead, dilute sulfuric acid (H2SO4) is typically used to acidify the KMnO4 solution, as it does not interfere with the redox reaction between KMnO4 and the analyte.
Is it possible to use HCL instead of h2so4 during kmno4 titration?
No, it is not recommended to use HCl instead of H2SO4 during KMnO4 titration. H2SO4 is preferred because it provides the necessary acidic conditions for the reaction to occur accurately. Using HCl may not yield reliable results as it might interfere with the reaction.
How do you calculate the moles of H2SO4 in a titration?
To calculate the moles of H2SO4 in a titration, you can use the formula: moles Molarity x Volume. First, determine the molarity of the H2SO4 solution. Then, measure the volume of the solution used in the titration. Multiply the molarity by the volume to find the moles of H2SO4.
Why you do not use H2SO4 in iodometric titration?
Using H2SO4 in iodometric titration can lead to the formation of H2O2, which interferes with the reaction. It can also oxidize iodide ions prematurely, affecting the accuracy of the titration. Therefore, a different acid like HCl is typically used in iodometric titration.
Why do you add H2SO4 instead of HCL in redox titration?
H2SO4 is preferred over HCl in redox titrations because HCl can release Cl2 gas during the reaction, which can interfere with the titration results. H2SO4 provides the necessary acidic conditions for the redox reaction without introducing additional complications.
Why HCL is not use to acidify KMnO4 soln in permanganometric titration?
HCl cannot be used to acidify KMnO4 solution in permanganometric titration because it will react with KMnO4 reducing it to MnO2, which interferes with the titration process and affects the accuracy of the results. Instead, dilute sulfuric acid (H2SO4) is typically used to acidify the KMnO4 solution, as it does not interfere with the redox reaction between KMnO4 and the analyte.
Is it possible to use HCL instead of h2so4 during kmno4 titration?
No, it is not recommended to use HCl instead of H2SO4 during KMnO4 titration. H2SO4 is preferred because it provides the necessary acidic conditions for the reaction to occur accurately. Using HCl may not yield reliable results as it might interfere with the reaction.
How do you calculate the moles of H2SO4 in a titration?
To calculate the moles of H2SO4 in a titration, you can use the formula: moles Molarity x Volume. First, determine the molarity of the H2SO4 solution. Then, measure the volume of the solution used in the titration. Multiply the molarity by the volume to find the moles of H2SO4.
Why you do not use H2SO4 in iodometric titration?
Using H2SO4 in iodometric titration can lead to the formation of H2O2, which interferes with the reaction. It can also oxidize iodide ions prematurely, affecting the accuracy of the titration. Therefore, a different acid like HCl is typically used in iodometric titration.
Why is dilute h2so4 most suitable as compared to hcl and hno3 in kmno4 titrarion?
Dilute H2SO4 is preferred over HCl and HNO3 in KMnO4 titrations because H2SO4 does not oxidize the Mn present in KMnO4, maintaining its stability. On the other hand, HCl and HNO3 can oxidize Mn in KMnO4, interfering with the titration results. Additionally, H2SO4 helps to acidify the solution and provide the necessary hydrogen ions for the reduction-oxidation reaction to proceed effectively.
Which indicator is used in titration of naoh and h2so4?
Phenolphthalein is commonly used as an indicator in the titration of NaOH and H2SO4. It changes color from colorless to pink as the solution reaches a specific pH range, signaling the endpoint of the titration.
Why use h2so4 instead of hcl in titration of kmno4?
H2SO4 is typically used instead of HCl in the titration of KMnO4 because HCl can react with KMnO4 and form chlorine gas, which can interfere with the titration results. Additionally, H2SO4 provides the required acidic medium for the reaction to occur between KMnO4 and the analyte.
What happens when a titration is done with Na2co3 in the biurrette and h2so4 in the flask?
When titrating Na2CO3 with H2SO4, the acid-base reaction that occurs is: Na2CO3 + H2SO4 → Na2SO4 + H2CO3 The carbonate ion (CO3^2-) in Na2CO3 reacts with the hydrogen ion (H+) in H2SO4 to form carbonic acid (H2CO3), which then decomposes into water (H2O) and carbon dioxide (CO2). The endpoint of the titration is reached when all the Na2CO3 has reacted with the H2SO4.
How do you standardize 1N H2SO4 with a KHP?
To standardize 1N H2SO4 with KHP, you would first prepare a solution of KHP of known concentration. Then, titrate the KHP solution with the 1N H2SO4 solution until the endpoint is reached. The volume of H2SO4 used in the titration can then be used to calculate the exact concentration of the H2SO4 solution.
Why KMnO4 titration's are carried out only in the presence of dilute H2SO4?
The permanganate ion, MnO4- purple in colour. The sulfuric acid is added to create acidic conditions. In acidic conditions, the MnO4- gets reduced to Mn2+ which is colourless. Therefore, judging by the colour change, we can figure out how much of the potassium permanganate has been used.
What is the concentration of the acid (H2SO4) in the following titration?
To determine the concentration of the acid (H2SO4) in a titration, you will need to know the volume of the acid used, the volume of the base added, and the molarity of the base. By using the balanced chemical equation of the reaction and the volume of the acid and base used, you can calculate the concentration of the acid.
