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You have to look at the molecular bonding of the two and the energy that can be released through bonds broken. Butanol releases a lot more energy when the bonds between the atoms in butanol are broken because there are more bonds to break. There are four carbons in butanol, with atomic formula CH3CH2CH2CH2OH, versus only one carbon in methanol, with formula CH3OH. There is simply more energy in butanol than in methanol. Look up molecular bonding energy for more information and an imperial answer.

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