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Al has atomic number 13, and silicon has atomic number 14. The extra electron that silicon has is in a 3p orbital. In simple terms the extra charge on the silicon nucleus contracts the electron shell, this increases the energy to remove an electron and also decreases the atomic radius.

Al, first ionization energy 577.5 kJ/mol, atomic radius 125pm

Si, first ionization energy 786.3 kJ/mol, atomic radius 110pm

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Q: Why is the first ionization energy of aluminium is less than the first ionisation energy of silicon?
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Is Aluminum low ionization energy?

The ionization energy of aluminium is 5,985 77 eV. It is a medium energy.


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