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Essentially the 3 basic parts to an atom are a Proton, Neutron and an Electron.

Protons have a unit of mass and a positive charge

Neutrons have a unit of mass and a neutral charge

Electrons have no unit of mass and a negative charge.

When a neutron breaks off from another atom it becomes a free radical that is then absorbed by the receiving atom because it would have a spare neutron space because the number of neutrons must be identical to the number of protons otherwise the atom will radioactivity decay.

Essentially the mass number changes because the neutron has a mass.

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