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Number of electrons in outer shell determines thechemical nature of the element and is unique per element. Effective Valence electrons is a calculated ratio between two concentrations of electrons. if n=resisitivity/(e*driftMobility)

and n_at=density*Avogadro#/AtomicMass. Effective valence electrons is then n/n_at. Rounding this number should agree with outer shell electrons as predicted from the Periodic Table.

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