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I believe that the most volatile substance in the world is Oxygen Argon Plasma however it depends on what you wish to make "go away" and in what manner. for sake of simplicity, I will stick to acids. hydrochloric acid is by far the most commonly known of dangerous substances however, hydrofluoric acid is known to pass through human tissue and liquify you from the inside out. if you want to know about a gruesome way to die, hydrofluoric acid is probably one of the best substances to use. Perchloric acid is an explosive. also in terms of most volatile substance possible (that is unproven) anti matter supposedly fits the bill, far surpassing any other substance, if it exists. over all however, I would stick to Oxygen-Argon plasma, it can break down anything it touches and must be contained in a magnetic field, however it cannot be stored so as for practicality in "making things go away", it scores fairly low.

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