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I am not an expert on this topic, but silicon I believe has access to some D orbitals. Water can exploit this D orbital and bond to the silicone producing an Si-O-H bond and HCl which fumes. I believe this is thermodynamically favorable (si-O-H). Carbon tetrachloride does not have access to D orbitals and can not form the necessary intermediate to react (kinetically hindered). That's my shot at it.

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13y ago

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