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The answer lies at the molecular level. When a substance is heated, the heat energy is absorbed by the molecules from which the substance is comprised. The heat energy is then transformed into the kinetic energy of the molecules - in other words they move faster. This motion of the molecules is referred to as Brownian motion. The motion of a molecule, however, is random and so it continually collides with other molecules.

Now imagine a fluid comprised of a dense cloud of molecules. As the molecules begin to collide with one another at a faster rate, they begin to push each other apart. Therefore, if you heat a cubic foot of molecules, some percentage of the total number gets pushed outside the cubic foot boundary. When there are fewer molecules in the cubic foot, the cubic foot weighs less than it did before it was heated - it becomes less dense.

It is worth noting here that water is a unique fluid. As it cools, it becomes more dense like every other substance. When it becomes solid (ice), though, it suddenly expands becoming less dense. That is why the stuff floats. If it didn't behave in this manner, lakes, rivers, and seas would freeze from the bottom up and marine life as we know it couldn't exist. That is another topic, though.

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Q: Why is warm fluid less dense than cool fluid?
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