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Actually, very little. Most people cannot tell the difference in taste, and they have virtually identical nutritional value. There is a rumor that black seeds help keep hair from turning grey only -- though I assume this is just an old wive's tale. In terms of usage, black sesame seeds are used more in the Far East in Asian food (often, they coat meat in them before grilling/sauteeing, whereas white are preferred in the Middle East, where they are often ground into tahini.

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