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Yes you need to weaken the opponent as much as you can then make it sleep or paralyze it then throw any pokeball. If the Pokemon is generally weaker (levels around 20) use a nest ball, If the Pokemon is one you have previously caught or have owned use a repeat ball, If the Pokemon is a Bug type or Water type or even both use a net ball, If the battle takes a long time use a timer ball it gets more effective the longer the battle lasts.

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