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Spock's blood is green.

It is green because the oxidizing agent in Vulcan blood, the base element of his hemoglobin, is copper, not iron as it is in humans. Copper oxide (verdigris) gave Spock's blood its blue-green hue. We see this on episode "Journey to Babel" when Spock's Vulcan father, Ambassador Sarek (Mark Lenard) suffers a heart attack that requires surgery and a life-giving transfusion of T- Negative blood from Spock.
In Star Trek The Original Series Dr. McCoy comments on Spock's Green Blood. Therefore his blood is Green.

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