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C6H6 is the molecule of benzene and it's molecular weight is 78, calculated as

6 x 12 +6 x 1=78

and you will understand it if you know some basics of chemistry.

then,

You know that each mole of a molecule weighs exactly those number of grams as much as is its molecular weight. That means if a molecule has 'M' as its molecular weight, then one mole of it weighs exactly M grams when actually weighed using a weighing machine.

This means one mole of benzene weighs 78 grams. then 195 grams of C6H6 has (1/78)x195 moles or 195/78 moles in it.

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