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Yes, as the water changes state from liquid to gas it has a high latent heat- meaning that heat is transferred from the skin to the atmosphere as the water evaporates, much in the same way sweating works. However this technique will only mildly lower the surface temperature of the body, if the body is suffering from heat exhaustion more extreme methods of lowering body temperature should be used such as using a cool shower. Note that cold water should not be used to lower the body temperature as it may cause vasconstriction of the capillaries near the skin which can have counter productive consequences.

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