Switzerland, in 2002. Switzerland last voted on UN entry during the Cold War in 1986 when the issue was defeated by 75% of voters. People feared that freedom and the rights would be limited, and neutrality would be deeply damaged. Joining UN would mean its traditional stance of neutrality would be compromised - in the event of Swiss troops being asked to be part of peacekeeping forces or asked by the Security Council to take up arms in foreign conflicts.
Afghanistan is the latest, joining in 2008.
Montenegro [2006] Montenegro [2006]
China x
Switzerland has not joined in the UN and it is only an observer country. Appart from having 'co-headquarters' of the UN in Geneva Switzerland has been a member of most UN suborganisations (and their mainsponsor!) for a long time. The country has joined the UN in 2002.
The Netherlands joined the UN on December 10, 1945.
Switzerland.
Ghana joined the United Nations on August 3, 1957.
No. They joined in 1955, and became the 15th member. There are now 28 members. Albania and Croatia both joined in 2009, becoming the latest members.
In 1949, no new countries joined the United Nations; however, the UN General Assembly did admit several nations in the years following its founding in 1945. Notably, the countries that joined in 1949 were not part of the UN until they were admitted later on. The most significant membership changes occurred in the years immediately following World War II, with many nations gaining independence and seeking UN membership thereafter.
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2 March, 1992 the Republic of Kazakhstan joined the UN.
Libya joined the UN on September 18th, 1990.