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It takes time (although usually a very small amount) for an enzyme molecule to catalyze a reaction. An enzyme solution is said to be saturated if all the molecules of enzyme in the solution are operating at full capacity (all active sites binding substrate molecules). Some enzymes are easily saturated (RuBisCo - 3 reactions/second) due to the highly energetically-demanding reactions that they catalyze while other enzymes that catalyze relatively simple reactions (amylase - many many reactions/second) are harder to saturate.

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