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a pH=10 solution of NaOH should contain 0,0001 moles of NaOH/liter. (1 mole/liter for pH=14, 0,1 for pH=13, etc.)

A mole of NaOH is 40g-s. (Na=23g O=16g H=1g) 0,0001 mole is 0,004gs.

You need the amount necessary for a quarter of a liter, so you divide by four. The result is that you need 0,001gs of NaOH.

So if you need to make that solution without any precise laboratory equipment, you should make much larger quantities and just measure 0,250 l-s.

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